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    Adam S. Hock, Ph.D.

    Adam S. Hock , Ph.D.

    Assistant Professor of Chemistry
    Assistant Scientist, Argonne National Laboratory

    Office: 156 Life Sciences Building
    Office Hours: TBA
    Phone: 312.567.3388
    Fax: 312.567.3494
    Email: ahock@iit.edu
    Web: click here

    Expertise

    • Inorganic and organometallic synthesis
    • Catalysis
    • Materials and Vapor Deposition

    Education

    • B.S. University of Delaware
    • Ph.D. Massachusetts Institute of Technology

    Curriculum Vitae

    Research & Major Accomplishments

    Our research interests include solar energy conversion, catalysis, electronic materials, and chemical structure and bonding.  Within this context we focus on developing rational synthetic methods to prepare earth-abundant and inexpensive materials for photon capture, innovative homogeneous and heterogeneous catalysts, and unique reactivity models.  We conduct highly collaborative research through our affiliation with Argonne National Laboratory.

    Students in the Hock group will learn to synthesize and characterize novel substances throughout the course of their research.   We routinely use techniques such as multi-nuclear NMR, UV-Vis spectroscopy, FTIR spectroscopy, and x-ray crystallography to characterize molecular substances.  The composition and properties of new materials are routinely determined by Rutherford Backscattering Spectroscopy (RBS), Scanning and Tunneling Electron Microscopy (SEM & TEM), and diffraction methods as well as optical, electrical, and other measurements where appropriate. 

    Current Projects

    Awards/Honors

    • 2009 Harvard University Competitive Postdoctoral Travel Award
    • 2009 Camille and Henry Dreyfus Environmental Chemistry Fellow, Harvard University

    Patents

    • Hock, A. S. and Godon, R. G. “Cyclic Amides and Vapor Deposition Using Them” (application #61/320069)
    • "Olefin metathesis catalysts and related methods" (application # 11/603951)

    Books

    Selected Publications

    Hock, A. S.; Schrock, R. R.; Hoveyda, A. H.  “Dipyrrolyl Precursors to Bisalkoxide Molybdenum Olefin Metathesis Catalysts”  J. Am. Chem. Soc. 2006128, 16373.

    Blanc, F., Thivolle-Cazat, J., Basset, J. M., Coperet, C., Hock, A. S., Tonzetich, Z. J., Schrock, R. R.   “Highly Active, Stable, and Selective Well-Defined Silica Supported Mo Imido Olefin Metathesis Catalysts”    J. Am. Chem. Soc2007129(5),  1044.

    Marinescu, S. M., Singh, R., Hock, A. S., Wampler, K. M., Schrock, R. R., and Müller, P.  “Syntheses and Structures of Molybdenum Imido Alkylidene Pyrrolide and Indolide Complexes”  Organometallics, 2008, 27, 6570.

    Hock, A. S. and Schrock, R. R.   “Oxidative reactions of the MoIV dialkyl complex [{(3-CF3C6H4NCH2CH2)2NMe}Mo(CH2SiMe3)2]”  Chemistry - An Asian Journal, 20072(7),  867.

    Heo, J., Hock, A. S., and Gordon, R. G.  "Low Temperature Atomic Layer Deposition of Tin Oxide", Chemistry of Materials, 2010, DOI: 10.1021/cm1011108.

    Professional Society Memberships

    Editorial Board Service

    Professional Society Service

    • ACS
    • MRS

    Grants

    Community Service

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